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| 708
East Broad Street |
Falls
Church, VA 22046-3610 |
| Tel: (703)
241-8711 |
Fax:
(703) 241-8714 |
www.ricllc.com |
RADIOACTIVE
ISOLATION CONSORTIUM, LLC
(RIC, LLC)
ADVANCED VITRIFICATION SYSTEM (RIC
AVS)
RESEARCH AND DEVELOPMENT PROJECT
(DE-AC26-98FT40450)
PHASE I
GATE 3 REQUIREMENTS, DELIVERABLES,
AND AVS EXPLORATORY DEVELOPMENT PROPOSED FINDINGS
SEPTEMBER 1999
RIC, LLC, 1655 N. Fort Myer
Drive, #900, Falls Church, VA 22046-3610
Tel: 703-241-8711 Fax: 703-241-8714
http://www.ricllc.com
Development of an Advanced Vitrification System –
Phase I
Exploratory Development Stage
DOE Award Number: DE-AC26-98FT40450
Topical Report Issued: April 2, 1999
Draft Addendum to the Report Issued September 1999
Co-Principal Investigators:
James R. Powell Morris Reich
Submitted by: James C. Jordan, President and CEO
Radioactive Isolation Consortium, LLC
708 East Broad Street,, Falls Church, VA 22046-3610
Tel: 703-241-8711
Significant Subcontractors: Argus Remediation
Technologies, Inc., Millersville, MD
Burns and Roe Enterprises, Inc., Oradell, NJ
UCAR Carbon Company, Inc., Clarksburg, WV
Auburn University, Auburn, AL
Mississippi State University, Starkville, MS
Corning Engineering Laboratory Services, NY
ABSTRACT
Vitrification of high-level nuclear wastes has long been thought to
represent the best technology for immobilization. Most successful
examples of this technology have been associated with the waste streams
from spent fuel reprocessing plants. In the U.S., the high-level waste
issue is more involved with the stabilization of the wastes generated
during the production of nuclear materials for national defense, and as
such, the waste characteristics have made a successful vitrification
process difficult to achieve. Congress mandated in recent funding
language that the U.S. Department of Energy (DOE) investigate unique and
innovative approaches to vitrification technology. The DOE awarded a
sole source contract to the Radioactive Isolation Consortium, LLC (RIC)
to develop and demonstrate its unique and innovative concept for
vitrifying high-level radioactive waste. This new concept provides a
unique approach to vitrification-in-the-final-storage-canister that
holds the potential for significantly greater safety, reliability, and
economy than current high-level radioactive waste vitrification systems.
The current contract is for the completion and demonstration of a half
scale operating prototype. This first phase of the RIC AVS project is
being approached in two Stages: (1) a fourteen-month stage (the
Exploratory Development Stage), and (2) an eighteen-month stage (the
Advanced Development Stage). This report documents the results of the
Exploratory Development Stage.
The Exploratory Development Stage produced high quality samples of
glass using a range of Hanford-based simulant compositions and
concentrations. The bench-scale samples have demonstrated the viability
of the RIC concept by making glass with excellent leach resistance
characteristics using waste concentrations of 100% by weight. In the
product glass these waste concentrations are 3 or more times greater
than the waste concentrations in glass made using conventional melters.
This RIC AVS capability can reduce the number of canisters needed to
dispose of the Hanford high level waste by a factor of 2 to 3.
Experimental results have also confirmed that the RIC AVS can
- vitrify caustic high level wastes with a pH up to 13.4,
- tolerate wide chemical variations in high level waste feeds, as is
present at Hanford,
- vitrify high level wastes with simpler waste pretreatment and
melter feed requirements, and
- greatly shorten the time required to vitrify all of Hanford’s
high level wastes.
The bench scale tests also validated the theoretical assumptions for
the subsequent engineering, fabrication, and manufacturing of the RIC
AVS. A pre-conceptual design of the full-scale embodiment of the RIC AVS
concept has been developed and has been used as the basis for a
preliminary life-cycle cost estimate that confirms that the RIC AVS
costs per unit of waste vitrified are less than half the costs per unit
vitrified of a continuous throughput conventional melter.
Project Goals
The project will prove that the Radioactive Isolation Consortium's
Advanced Vitrification System (RIC AVS) technology will produce HLW
glass suitable for long-term storage and disposal while achieving
significant cost savings a faster campaign schedule and improved safety.
DOE's award to the Radioactive Isolation Consortium (RIC) is to
complete validation tests in Phase I by building and operating a
half-scale prototype of the RIC AVS Module.
Phase I is a two-stage approach to the proof of principle of the RIC
AVS technology. Stage I, termed the "Exploratory Development
Stage," has been funded at $2 million and is completed with this
report.
Stage I produced glass utilizing a Department of Energy (DOE)
designated surrogate of Hanford Tank Wastes.
Stage II, termed the "Engineering Development Stage," has
been funded at $12 million and will be completed about 18 months after
start. Stage II will produce and operate a half-scale prototype of the
RIC-Advanced Vitrification System technology. The completion of Stage II
RIC plans to offer DOE a competitive privatization proposal for work at
Hanford.
Phase II of the project will produce and test a full-scale RIC AVS
Module which will be capable of hot operations at Hanford. The Phase II
project cost is estimated at $72 million (FY 1997 dollars) and will be a
part of the privatization proposal with funding expected from DOE.
Phase I Stage I work included validation and data gathering
bench-scale tests, preparation of a pre-conceptual design of the
baseline full-scale RIC AVS facility, and preparation of a facility
life-cycle cost estimate.
Successful testing and design work resulted in initial
projections for completing all high level waste vitrification work at
Hanford using the RIC AVS at less than half the cost projected for the
planned continuous throughput melter and being completed in about 12
years rather than 30 or more years currently planned.
Gate 3 Review Deliverables
The documentation/deliverables summarized below address the
criteria/requirements required by the U.S. Department of Energy (DOE) to
evaluate the results of the Exploratory Development Stage of the
Advanced Vitrification System (RIC AVS) Phase 1 Program. The evaluation
is officially termed a "Gate 3" review.
The detail provided in the deliverables reflects the status of the
technology at time of entry into the Gate 3 review. Each of the 6
Programmatic Driver Criteria is discussed in the following subsections.
Table 1.3.1-1 is a compliance matrix in which the Gate 3 required
deliverables are identified by reference to the appropriate section
within this report.
Programmatic Driver Criterion: Technology End User Need
Requirement
- Project must be relevant to a defined high-priority DOE
environmental management need.
Deliverable
- The Technology Developer/Principal Investigator (TD/PI) must
show how the proposed technology is tied directly to one or more of
these needs.
Background
- The Focus Area/Crosscutting Programs/Industry Programs
(FA/CC/IP) will develop a high-priority Department of Energy, Office
of Environmental Management needs list for their respective program
from the information gathered on the needs template established by
the Site Technology Coordinating Groups (STCGs). This will include
the priority of the need, required implementation dates, baseline
technology, performance requirements, and associated costs.
FINDINGS
- The Technology is directly tied to the high-priority environmental
management need to isolate high level radioactive wastes (HLW) from
the biosphere.
- RIC (the TD/PI) has demonstrated that its Advanced Vitrification
System (RIC AVS) is tied directly to the cleanup of the Hanford tank
wastes. Simulated wastes to DOE's specifications have been vitrified
using the RIC AVS technology.
- The unique and inherent capability of the RIC AVS technology to
routinely vitrify a wide variety of chemically complex high level
wastes matches the requirements for vitrifying Hanford wastes, which
are known to vary in chemical composition from tank to tank, within
the tanks, and over time as the wastes age.
- This unique and inherent capability is due first to the fact that
the RIC AVS is a "single batch disposable melter." Single
batch means that the chemistry of the wastes is almost irrelevant in
terms of the deleterious effects on the life of the melter. It is
important only insofar as the RIC AVS melter can operate for several
days, that is, as long as it takes to vitrify the single batch. The
RIC AVS melter does not have to be preserved for years of operation
as is required for the continuous melter. Use the RIC AVS melter
once and it is done. This removes process control limitations
currently causing much of the expense and risk of failure for the
continuous melter.
- Secondly, the unique and inherent capability is due the high
vitrification temperatures permitted in the RIC AVS. The operating
envelope for the RIC AVS can be as low as the continuous melter,
around 1150 degrees Centigrade. It can also be as high as 1600
degrees Centigrade.
- Higher vitrification temperatures are beneficial in three
respects--
- They permit loading the glass to with 70 to 100 percent waste, the
remaining part being glass inducing chemicals.
- They permit melting waste compositions having high melting
points.
- They permit the formation of a more durable (leach resistant)
glass.
- Operation at melt temperatures of 1400 -1600 degrees Centigrade is
not practicable for a continuous melter, because the continuous
melter’s lifetime would diminish from years to days. When one is
not concerned with preserving the lifetime of the melter beyond a
few days, as the case with the RIC AVS, which need operate through
only one melt process, then high temperatures are possible on a
routine basis.
- There is a large economic cost to the Government associated with
the continuous melter technology due to the waste blending process
step and the waste pretreatment process step to bring the waste
chemistry within contractual delivery requirements. Such process
steps can be expensive as they contemplate the construction of large
blending tanks and miles of associated piping. Since the RIC AVS
technology can enlarge the field of acceptable waste chemistries,
then such operating flexibility eliminates a burden on the
government concerning meeting such delivery requirements. This
burden is not only a costly process step subject to failures, it is
also a source of economic and environmental liability. If conforming
wastes cannot be delivered on time, DOE will be liable for the delay
costs. Also, no complex chemical process is without risk of
pollution and damage to the environment.
- Limited blending might be anticipated in the RIC AVS in order to
increase the HLW content of the waste mixture, to permit the
vitrification of a higher waste loaded glass, or in very limited
circumstances to reduce the concentration of elements precluding the
formation of glass in the 1150-1600 degrees Centigrade operating
envelope of the RIC AVS.
1.1.2 Priority of the Need -- The Hanford waste "poses a serious
safety concern to the public and to the environment . . . . DOE, State
regulatory agencies, and stakeholders view the tank waste cleanup as one
of their top priorities." DOE Report to Congress, Treatment and
Immobilization of Hanford Radioactive Tank Waste, July 1998. The
national policy for development of high-payback research on this issue
was first set by Congress FY 1997. For each year, beginning in FY 1997,
the Congress of the United States recommended in the conference reports
to the Energy and Water Development Appropriation Acts that the
Department of Energy conduct research on higher risk, high-payback
processing and vitrification technologies such as the RIC AVS
technology.
Required Implementation Dates - The current implementation date
projected by DOE under the "Privatization" agreement with the
British Nuclear Fuels Limited (BNFL) group for start of the
vitrification of HLW at Hanford is projected for 2007. Thereafter, in
2018, a minimum of 10 percent of the tank wastes will be vitrified.
Using baseline technology, it might be expected that the remaining 90%
of the tank wastes could be vitrified over an additional 30 years. The
RIC AVS technology is projected to advance the initiation of HLW
vitrification at Hanford by three years and could shorten the campaign
by 4 decades, resulting in all of the waste being vitrified in only 12
years, instead of 50. One commercial size (12 modules) RIC AVS facility
could vitrify all of Hanford’s HLW in 4 years of operation. This rate
assumes a commerical size facility would produce at a rate of 4
canisters per day. The single RIC AVS prototype unit is scheduled for
completion in 2004 and could run hot thereafter, producing a canister of
waste every 3 days. Such operation in 2004 would advance the schedule
for hot operations by 2 years.
Baseline Technology
- The current DOE baseline technology is vitrification of HLW by
mixing with borosilicate glass. Baseline technology also employs a
central vitrifier and the melted mix is poured into the
container.
- The baseline RIC AVS technology also involves mixing radioactive
waste with borosilicate glass. The RIC AVS directly melts the waste
frit feed in the final disposal container with no need for further
processing.
- The current DOE baseline centralized melter is subject to failures
that can stop processing operations and be costly to repair. The
one-time-use RIC AVS eliminates this failure and repair
mechanism.
- The current DOE baseline centralized melter operates over long
periods and therefore has certain operating limits that reduce its
efficiency.
- The first example is the limitation on the chemical content of
the waste as a feed to the centralized melter necessitates
pretreatment of the wastes, which can be costly. The RIC AVS
only operates the melter once in the canister, so it has a much
higher tolerance for variations in the chemical composition of
the waste reducing the need for costly and extensive
pretreatment.
- The second example is the combination of the chemical
sensitivity of the centralized melter to changes in waste
composition and the limit on the highest melt temperature
achievable in a centralized melter. These factors place a limit
on the maximum waste loading that can be generated in the glass
product and therefore a maximum waste content per container.
The limit of the amount of waste in the waste form for the
centralized melter is about 25% if the waste does not contain
large amounts of silica. This value is determined by limits
related to the safe and economic operation of the melter rather
than by limits imposed by wasteform properties.
At Hanford where some of the waste contains large quantities of
glass formers such as silica and sodium oxide, the centralized
melter actual waste loading may be as high as 50% while the
"reduced" waste loading (ignoring the sodium and
silicon oxide concentrations in the glass) remains about 25%.
In comparison the RIC AVS technology has experimentally
demonstrated the capability to produce a vitrified leach
resistant glass of 100% actual waste loading from the Hanford
waste with about 60% "reduced" waste loading.
The AVS is projected to have the capability of making a
wasteform with only 20% silica, indicating that
"reduced" waste loadings of about 80% are achievable.
This is to be compared to the centralized melter, which is
limited to a maximum "reduced" waste loading of 25%
because of the technology limitations noted above. These
favorable comparisons are achieved because the RIC AVS
technology uses the melter only once so it has a much higher
tolerance for the chemical content of the waste and can achieve
a melt temperature about 1/3 higher than the centralized
melter.
- Finally, in the RIC AVS technology the steel container is
maintained at close to room temperature and thus the material
properties of the steel are not affected by the high
temperatures of the poured glass as they are in the baseline
centralized melter technology. This should translate into a
higher lifetime of the steel container in the final disposal
repository.
Associated Costs
- It has been demonstrated that the RIC AVS technology can vitrify
a 100% waste glass with no frit or other additives. In the event
that frit is required for some waste chemistries, it is
anticipated that the higher waste loading will provide a 3 to 1
advantage in disposal costs. A smaller facility, one that requires
little chemical melter feed preparation, and one that eliminates
decontamination and decommissioning costs of the melter is
projected to reduce operating costs by a factor of 2.
- The RIC AVS technology is cost effective. A recent life cycle
cost comparison of the RIC AVS and with published costs of the
systems at Savannah River and the projected costs of the
Privatization Contractor Group at Hanford reveal the dramatically
favorable costs that could be achieved by the RIC AVS:
| Projected Life Cycle Costs at
Design Throughput in $/Kg HLW |
| Advanced Vitrification System (RIC
AVS) |
$459 |
| Current Privatization Contract at
Hanford Site |
$1,200 |
| DWPF at Savannah River Site |
$2,400 |
Requirement
- Research will yield results within a time frame consistent
with implementation/deployment needs.
Deliverable
- The TD/PI must provide evidence that the research and
development of the technology has a high probability of completion
within the required implementation/deployment time frame.
Background
- The required implementation dates for the technology will be
provided by the (FA/CC/IP).
FINDINGS
The Technology will yield results within a time frame consistent
with implementation/ deployment needs.
- The RIC AVS technology is timely in that it is on a development
schedule for possible implementation faster than traditional
technology: A half-scale operating prototype is scheduled for
operability by April 2001 and a full-scale operating prototype is
scheduled to be built and operating in Hanford by April 2004. The
single RIC AVS prototype unit scheduled for completion in 2004 and
could run hot thereafter, producing a canister of waste every 3
days. Such operation in 2004 would advance the schedule for hot
operations by 2 years.
- High Probability of Completion -- The RIC AVS technology
combines existing technology in an innovative and useful way.
Additional engineering development work is required, but is
thought to be well within the existing technology base. No leap of
science or technology is required.
 |
 |
| The above photographs show long graphite tubes
and thin-walled sections of tubes in production at UCAR
Carbon Company of West Virginia. The size and shape of these
tubes is comparable to that required in the RIC AVS. |
|
- Therefore, completion within the projected time frame has a high
probability of success. Additionally, a full scale RIC AVS
facility would have the capability to complete the Hanford HLW
vitrification campaign within 4 years of initial operation as
opposed to 30 or more years with traditional technology.
Programmatic Driver Criterion: Technical Merit
Requirement
- Scientific and/or technical merit of the project must be well
founded.
- Likelihood is high that the research will lead to new
discoveries or have substantial impact on progress in that field.
Deliverable
- The TD/PI should emphasize the innovative aspects of the
technology.
Requirement
- Proposed methods or approach for demonstration and
implementation are scientifically based.
Deliverable
- The TD/PI must discuss the appropriateness of the research as
it relates to acceptable technical practices.
Requirement
- Potential technical advantage(s) over baseline and/or
alternative technologies must be well defined.
Deliverable
- The TD/PI must provide evidence that the technology has
technical advantages over the baseline and/or alternative
technologies.
Background
- The baseline technology will be provided by the FA/CC/IP in
concert with the STCG and site.
FINDINGS
The Technology proposed for development has scientific and
technical merit.
- Scientific and Technical Merit -- The testing performed in the
Exploratory Development Stage demonstrated the flexibility of the
RIC AVS concept, and it has also demonstrated the superiority of
the RIC AVS technology in producing high waste loadings with
little or no waste pretreatment and melter feed preparation.
The results from the RIC AVS Exploratory Development Stage
indicates significant advantages over the present conventional melter
system in terms of--
1. Greater operating reliability and safety the pre-conceptual
design of the RIC AVS module and vitrification facility is based on 12
paralleled single cells that process RIC AVS modules.
- Failure of an induction heating coil or cooling circuit in one
of the process cells will not significantly impact the ability of
the facility to continue to process modules, in contrast to the
conventional large melter, where failure of a unit will shut down
or seriously degrade plant capacity.
- Failure of an RIC AVS module will not shut down the ability of a
process cell to continue operation, since the modules are
self-contained unit that can be readily removed from the
cell.
- A disposable melter in the RIC AVS dramatically reduces the
possibility of a melt processing accident as have occurred with
conventional melters. It eliminates the possibility of failure
resulting from electrode failure (there are no electrodes), and
plugging (there is no melt pouring).
2. Tests of the RIC AVS vitrified waste products have demonstrated
excellent PCT performance, being one to two orders of magnitude more
leach resistant the standard EA waste glass product.
3. RIC AVS tests have demonstrated much higher HLW loading than
possible with conventional melters.
- A waste loading of 100% was demonstrated in the supplemental
test. This capability is due to operability at temperatures of
about 1600ºC. Conventional melters are limited to about 29% HLW
loading in borosilicate glass and a maximum operating temperature
generally fixed at about 1200ºC. The RIC AVS has only short
maximum temperature exposure time before its crucible is disposed
of with the melt. The conventional crucible must last years in
operation. This high loading capability result in the RIC AVS
requiring two to three times fewer canisters to dispose of the
same quantity of HLW.
4. The RIC AVS experimental tests have demonstrated a capability to
handle HLW of a wide range of feed compositions--
- This includes wastes with problem elements such as Cr and Zr.
The glass product produced with varying compositions had excellent
leach resistance. The import of this attribute is that extensive
blending of tank wastes, which is a necessity for conventional
melters operating in Hanford wastes, is not required for the RIC
AVS.
- The batch melt process which operates only for a short period of
time. Also there are no critical failure-prone components, such as
the electrodes, and no sensitive process constraints, such as cold
caps. The import of this is that DOE can plan to address the
wastes an individual tank basis, making the whole process more
manageable and reliable.
- There is process flexibility to vitrify high alkaline pH,
neutral pH, or acid pH wastes. The RIC AVS eliminates process
requirements for adjusting the pH of the feed.
5. A faster Hanford campaign is possible using the RIC AVS.
The pre-conceptual RIC AVS facility design, which has an output
capacity of 4 modules per day, could vitrify all of Hanford’s HLW
waste in only 4 years—a faster rate than possible with conventional
melters. Others factors, such as tank retrieval rates are likely to
gait campaign time however, the RIC AVS vitrification system can meet
any Hanford cleanup schedule likely to be imposed.
6. There is significant cost savings potential over a conventional
melter system. Cost factors in comparison the continuous melter—
- Lower capital costs
- Smaller operating staff due to a simpler flowsheet and smaller
facility
- Smaller D&D costs due to the smaller radiological foot
print
- Projected cost per kg of vitrified HLW are about one-half of a
conventional melter.
- Fewer canisters will be sent to the repository for the same
quantity of waste. For every percentage point higher in waste
loading than a conventional melter, Secretary Moniz estimated
savings on the order of $250 million. If a conventional melter is
29% waste loading and RIC AVS is 80% waste loaded, that translates
into a savings potential of $12.7 billion.
- The testing program vindicated earlier technical reviews on the
RIC AVS technology. The technical review performed in February
1998 favorably resulted in the award of a contract from DOE. Prior
to that, an independent technical review before a panel of the
American Society of Mechanical Engineers established by the DOE in
1997 concluded that the technology has "merit," "is
relevant to DOE needs," and is "scientifically
sound." Prior to that, the RIC AVS technology was also
reviewed by the Chairman and staff of the Defense Nuclear Facility
Safety Board, who concluded that "there are sufficient
potential advantages to warrant a feasibility study including
proof of principle tests."
- RIC AVS system operability issues are within normal engineering
risks for the technology and the Exploratory Development Stage did
not identify any significant developmental barriers.
- The aforementioned safety, environmental and economic benefits
of the RIC AVS included with RIC’s commitment to provide a
privatization contract proposal at the end of Stage 2 make for a
compelling technical and programmatic case that the RIC AVS
project should proceed to the next stage, without delay.
Programmatic Driver Criterion: Cost
Requirement
- The proposed budget for research is reasonable.
Deliverable
- The TD/PI must show the budget for the life of the project
broken down on an annual basis. An estimated budget with major
elements identified and costed for the research through Stage 3
must be provided.
FINDINGS
- RIC AVS Technology Development Plan and Budget Overview is shown
in the table on the next page. It shows a Stage 2 Advanced
Development Stage costing $12 million. At the end of Stage 2, RIC
will be prepared to offer the DOE a privatization contract similar
to the DOE-BNFL privatization contract at Hanford. The contract
would include a DOE funded development stage of $72 million after
which RIC would privately finance the full scale AVS facility. The
price for vitrification is expected to be in the neighborhood of
$459 per kilogram of delivered vitrified HLW.
| AVS Technology Development Plan and
Budget Overview |
| Engineering Development
And Demonstration |
Implementation |
| Pre-Conceptual Design |
Conceptual Design |
Prelim And Final Design |
| Exploratory Development
Stage |
Advanced Development
Stage |
Engineering Development
Stage |
Capital Project Stage |
| Bench Scale Tests, Heat Transfer
Analyses, Waste Chemistry |
Gate 3 |
Construction And Operation Of A
One-Half Scale Pilot Modular, Pre-Conceptual Design And Cost
Estimate |
Gate 4 |
Construction And Operation Of
Full-Scale Hot Pilot Modular Unit, Conceptual Design Report |
Gate 5 |
Full-Scale Operational Facility
Design And Construction |
Gate 6 |
| 7 Months |
9/99 |
18 Months |
04/01 |
36 Months |
04/04 |
42 Months |
10/07 |
| $2 Million |
$1.2 Million |
$12.0 Million |
|
$72 Million |
|
$236 Million |
|
Bench-Scale Test Apparatus. 16 Test Results
With Varying Surrogate Waste Content Up To 80% And pH Values Up
To 13.4 Were Obtained.
|
Cut-Away Of The RIC AVS Module Showing From
Inside Out: Red Molten Glass, Light Gray Alumina Liner, Thin
Wall Graphite Crucible, High Per-Formance Insulation In The SS
Canister Surrounded By Coils.
|

Cut-Away Of Full-Scale, Single Module, Pilot
Plant To Be Built Near A Waste Storage Tank To Demonstrate The
Viability Of The AVS Concept With Real Tank Waste.
|
Conceptual View Of The RIC AVS Operating
Facility Showing The Bridge Crane Transporting An AVS Module To
A Fill And Melt Station. Facility Operating Rate: 4 Modules Per
Day.
|
Programmatic Driver Criterion: Safety, Health, Environmental
Protection, and Risk
Requirement
- The research must present a solution that meets or exceeds
current safety, health and environmental protection levels and
meets or reduces the risk to the public, workers, and the
environment during operation in comparison to baseline and
alternative technologies.
Deliverables
- The TD/PI must discuss how the research to date has
demonstrated the likelihood that safety, health, and environmental
protection levels will be maintained or exceeded and that risk to
the public, workers, and the environment will be maintained or
reduced.
Background
- The baseline technology will be provided by FA/CC/IP in
concert with the STCG and site.
FINDINGS
A study of the comparative features of the RIC AVS and the Baseline
Large Central Vitrifier Systems has found that there is a potential
for substantial improvements to Safety, Health, and Environmental
Protection, and Risk from the following contributions:
- Significant reduction in the radioactive footprint of the RIC
AVS facility
- Significant reduction to worker and environmental exposure
because the clean-up campaign is reduced by nearly 3
decades.
- The potential hazards extant at Hanford are mitigated much
faster with the RIC AVS technology.
- The RIC AVS's alumina and graphite liner in addition to
providing the functionality for vitrification has the potential to
qualify as an additional engineered barrier for long term geologic
storage.
- The outer steel liner stays near ambient temperature and thus is
unaffected by the process heating. This feature is expected to
result in a longer storage for the steel container.
Programmatic Driver Criterion: Stakeholder, Regulatory, and
Tribal Issues.
Requirement
- Stakeholder, regulator, and tribal issues associated with
similar technologies have been identified and assessed.
Deliverable
- The TD/PI must provide evidence that each of the issues
associated with similar technologies under this driver criterion
have been identified and assessed.
Background
- The FA/CA/IP, with support from the STCGs and the sites, will
provide input for these issues.
Requirement
- Appropriate notification and permitting requirements must be
identified.
Deliverable
- The TD/PI must provide evidence that notification and
permitting requirements for using the technology have been
identified.
FINDINGS
- Stakeholders and Regulatory Issues -- The National Environmental
Policy Act (NEPA) and the Washington State Environmental Policy
Act (SEPA) implementing regulations require that Federal agencies
consult with Federal, State, and local agencies and Tribes (as
appropriate) regarding significant proposed actions at Hanford.
The Tri-Cities Metropolitan Statistical Area (MSA), which
encompasses all of Benton and Franklin counties have stakeholder
interest in significant proposed actions at Hanford. Other
stakeholders are The Hanford Advisory Board, Hanford Health
Effects Subcommittee, State of Washington Military Department
Emergency Management Division, The Oregon Office of Energy, The
Oregon Hanford Waste Board, The Hanford Health Information
Network, The Hanford Health Information Archives, U.S. Defense
Nuclear Facilities Safety Board, The Washington State Department
of Ecology (Ecology), Department of Fish and Wildlife, Department
of Transportation, Department of Health, The Washington State
Governor's Office and Legislature, The Confederated Tribes and
Bands of the Yakima Indian Nation, The Confederated Tribes of the
Umatilla Indian Nation, The Nez Perce Tribe, and The Wanapum
People, The U.S. Nuclear Regulatory Commission (future
regulation), the U.S. Environmental Protection Agency
(environmental protection), the U.S. Department of Interior,
Bureau of Land Management (future land management), the U.S. Fish
and Wildlife Service (endangered species protection), and 17
public interest groups.
- Pursuant to the Atomic Energy Act, either DOE or the Nuclear
Regulatory Commission (NRC) serves as regulator for all
radiological and nuclear safety regulation in the United States.
The NRC currently has an advisory role at Hanford formalized by
Memoranda of Agreement and Understanding between the DOE Assistant
Secretaries for Environment, Safety and Health; and Environmental
Management and the Director of Nuclear Materials Safety and
Safeguards of the NRC.
- In general terms, the State and local stakeholder interests can
also be described in terms of the Hanford Federal Facility
Agreement and Consent Order (Tri-Party Agreement)
milestones.
- Tri-Party Milestones -- The RIC AVS technology with its
potential to accept a widely varying waste feed has potential to
assist DOE in meeting the Tri-Party Agreement milestone schedules
currently considered uncertain. The recognized uncertainties in
the milestone schedule of the Tri-Party Agreement arise from
problems in fully understanding tank waste characterization and
waste loading. The RIC AVS technology's ability to achieve a
higher percentage of waste loading (70-100%) than projected under
the baseline (25%) could speed the potential vitrification
campaign by decades. Also, its smaller processing facilities could
be constructed on faster schedules than possible with the large
central vitrifiers currently planned.
- Lower Staffing -- Preliminary engineering projections for the
RIC AVS technology show a significantly smaller on-site project
staff numbering about a few hundred rather than approximately one
thousand currently planned for the baseline high-level waste
vitrification technologies. This lower staffing level causes
uncertainties associated with the projection of future levels of
non-TWRS Hanford Site employment and future overall employment in
the Tri-Cities MSA. Future overall employment would be reduced
with the RIC AVS technology, which will require smaller federal
appropriations, but which will also have impacts on future Hanford
Site employment, Tri-Cities MSA non-farm employment, population,
taxable retail sales, and average home prices.
- Environmental Protection -- The stakeholders concerned with
environmental protection from radioactive and non-radioactive
emissions will be served by the RIC AVS technology because of:
- A smaller environmental impact (due to a small building
footprint and a system which minimizes waste blending,
pretreatment and spillage),
- A faster vitrification campaign (which minimizes environmental
risks due to tank leakage),
- The low temperature steel container (which avoids the steel's
physical deterioration from interaction with the hot glass),
and,
- The added engineered barrier of an integral graphite and
alumina container capable of containment of the waste over
geologic periods.
- Radiological and Nuclear Safety -- The RIC AVS technology
promises to enhance radiological and nuclear safety at
Hanford.
- Pretreatment Benefits -- The ability of the RIC AVS technology
to accept high pH or caustic wastes without neutralization
eliminates complex nuclear waste pretreatment and melter feed
preparation that is required using the baseline technology.
Similarly, the ability of the RIC AVS technology to accept a wide
chemical variability of the waste feed, reduces the complexity of
chemical pretreatment and melter feed preparation. Elimination of
a waste pretreatment step and reduction in complexity of melter
feed preparation, reduces the risk of radiological contamination
and accidents attendant with this process step.
- Process Benefits -- The RIC AVS technology eliminates a hot pour
of melted glass and waste into the disposal canister currently
anticipated using the baseline technology. The hot pour is a
source of ex-canister contamination and a failure point that leads
to high doses and additional contamination from repair,
maintenance and cleanup. The hot pour is also a source of the
impairment of the physical containment properties of the steel
container. This source of radiological contamination and nuclear
safety risk is eliminated using the RIC AVS technology.
- Reliability Benefits -- The RIC AVS technology is projected to
be more operationally reliable than traditional melter technology
because the potential for a single point of failure that would
cause a shut down in operations has been eliminated. A known
radiological and nuclear safety risk with the baseline technology
is operational reliability of the melter. The RIC AVS technology's
improved operational reliability reduces risk of radiological
contamination associated with maintenance and repair efforts.
- Canister Minimization -- The ability of the RIC AVS technology
to contain a high percentage of waste (70-100%) in each canister
provides enhanced radiological and nuclear safety. Fewer final
disposal canisters present less risk, and the higher waste loading
reduces the emission of off-gases during the melting
process.
- Engineered Barrier --Finally, the RIC AVS technology maintains a
separate high integrity inner container of graphite that has
potential to remain intact for geologic periods. The second
container provides a enhanced radiological containment and nuclear
safety completely absent in the current baseline design. The
graphite container also has added environmental benefits for
containment of included toxic or hazardous substances.
- Stakeholder Conclusion --For the foregoing reasons, stakeholder
interest in Hanford should be well served by the RIC AVS
technology in all cases except that a smaller work force and a
faster cleanup campaign will diminish the flow of economic
benefits to the local communities from nuclear waste clean-up
activities. However, eliminating the threat of radiological
contamination of the area's natural resources and fisheries will
have major positive economic benefits for the state and the
region.
Programmatic Driver Criterion: Commercial Viability
Requirement
- A preliminary product concept has been defined.
Deliverable
- The TD/PI must provide a discussion of the preliminary
product concept.
Requirement
- Invention disclosure and intellectual property issues have
been identified and protected as appropriate.
Deliverable
- The TD/PI must provide evidence that invention disclosures
and intellectual property issues have been identified and
protected as appropriate.
FINDINGS
- The experimentation program for the RIC AVS technology confirmed
its potential as an effective system for safe and economical
vitrification of a wide variety of highly corrosive radioactive
waste surrogate feeds. There are no "show stoppers" to
the continued development of the RIC AVS technology. The modular,
high operating temperature attributes of the RIC AVS technology
create the potential for several applications that can be
developed, for example:
- a transportable single module processing unit for small
batches
- a module scaled for operations in a hot cell
- a module with a different interior frit configuration to
isolate plutonium, cesium or clad wastes
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